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Factory Sells Best Quality 2-Thienyllithium 2786-07-4 with USP

  • Molecular Formula: C4H3LiS
  • Molecular Weight: 90.0748
  • Flash Point: −22 °F  
  • PSA: 28.24000 
  • Density: 0.829 g/mL at 25 °C  
  • LogP: 1.54830 

2-Thienyllithium(Cas 2786-07-4) Usage

InChI:InChI=1/C4H3S.Li/c1-2-4-5-3-1;/h1-3H;/rC4H3LiS/c5-4-2-1-3-6-4/h1-3H

2786-07-4 Relevant articles

Cocondensation reactions of heterocyclic aromatic compounds with lithium, calcium and magnesium atoms at 77 K

Mendoza, Oscar,Tacke, Matthias

, p. 1110 - 1116 (2006)

Calcium and magnesium atoms were coconde...

Cocondensation reactions of five-membered heterocycles with lithium atoms at 77 K

Mendoza, Oscar,Rehmann, Franz-Josef K.,Cuffe, Laurence P.,Tacke, Matthias

, p. 4525 - 4532 (2004)

Lithium atoms were cocondensed with eigh...

-

Gilman,Shirley

, p. 1870 (1949)

-

Electrophilic 2-thienylselenenylation of thiophene. Preparation of oligo(seleno-2,5-thienylenes)

Tiecco, Marcello,Testaferri, Lorenzo,Bagnoli, Luana,Marini, Francesca,Temperini, Andrea,Tomassini, Cristina,Santi, Claudio

, p. 3255 - 3260 (2000)

The substitution reactions of thiophene ...

Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone-Pair???π Interaction

Slavov, Chavdar,Yang, Chong,Heindl, Andreas H.,Wegner, Hermann A.,Dreuw, Andreas,Wachtveitl, Josef

, p. 380 - 387 (2020)

Azoheteroarene photoswitches have attrac...

Rhodium-Catalyzed Intermolecular Silylation of Csp?H by Silacyclobutanes

He, Tao,Li, Bin,Liu, Lichuan,Ma, Wenpeng,He, Wei

supporting information, p. 5648 - 5652 (2021/03/08)

The signature reactivity of silacyclobut...

LIPIDIC FURAN, PYRROLE, AND THIOPHENE COMPOUNDS FOR USE IN THE TREATMENT OF ATROPHIC VAGINITIS

-

Paragraph 0181; 0182; 0183; 0184; 0185, (2017/11/16)

Provided herein are lipidic furan, pyrro...

Synthesis of Benzosiloles by Intramolecular anti-Hydroarylation via ortho-C-H Activation of Aryloxyethynyl Silanes

Minami, Yasunori,Noguchi, Yuta,Hiyama, Tamejiro

supporting information, p. 14013 - 14016 (2017/10/17)

Straightforward synthesis of benzosilole...

2786-07-4 Process route

thiophene
188290-36-0,8014-23-1,25233-34-5

thiophene

2-thienyl lithium
2786-07-4

2-thienyl lithium

Conditions
Conditions Yield
With tetrahydrofuran; lithium; at -196.15 ℃;
55%
With n-butyllithium; In tetrahydrofuran;
With n-butyllithium; In tetrahydrofuran; 1. -78 deg C, 15 min, 2. -23 deg C, 30 min;
With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 1h;
With n-butyllithium; In tetrahydrofuran; hexane;
With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃;
With lithium; In tetrahydrofuran;
With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.583333h;
With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 2h;
With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 3h;
With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere; Schlenk technique;
With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;
With n-butyllithium; In cyclohexane; at 10 - 20 ℃; for 2h;
With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h; Inert atmosphere; Schlenk technique;
With n-butyllithium; In tetrahydrofuran; hexane;
thiophene
188290-36-0,8014-23-1,25233-34-5

thiophene

n-butyllithium
109-72-8,29786-93-4

n-butyllithium

2-thienyl lithium
2786-07-4

2-thienyl lithium

Conditions
Conditions Yield
With diethyl ether;
In tetrahydrofuran; at -40 ℃; for 1h;
In tetrahydrofuran; hexanes; for 0.5h;

2786-07-4 Upstream products

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    188290-36-0

    thiophene

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    n-butyllithium

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    2-bromothiophene

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    3437-95-4

    2-Iodothiophene

2786-07-4 Downstream products

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    6165-68-0

    thiophene boronic acid

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    100885-90-3

    2-methyl-2-phenyl-1-[2]thienyl-propan-1-one

  • 101431-05-4
    101431-05-4

    2-ethyl-2-phenyl-1-[2]thienyl-butan-1-one

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