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Buy Good Quality BIS(CYCLOPENTADIENYL)RUTHENIUM 1287-13-4 with a minimum purity of 99%
- Molecular Formula:C10H10Ru
- Molecular Weight:231.259
- Appearance/Colour:white to light brown crystals
- Vapor Pressure:418mmHg at 25°C
- Melting Point:199-201 °C
- Boiling Point:41.5 °C at 760 mmHg
BIS(CYCLOPENTADIENYL)RUTHENIUM(Cas 1287-13-4) Usage
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Purification Methods |
Sublime it in high vacuum at 120o. It forms yellow crystals which can be recrystallised from CCl4 as transparent plates. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 16 IV 1833.] |
InChI:InChI=1/2C5H5.Ru/c2*1-2-4-5-3-1;/h2*1-5H;/q-5;-1;
1287-13-4 Relevant articles
One-electron oxidation of ruthenocene: Reactions of the ruthenocenium ion in gentle electrolyte media
Swarts, Jannie C.,Nafady, Ayman,Roudebush, John H.,Trupia, Sabrina,Geiger, William E.
, p. 2156 - 2165 (2009)
The electrochemical oxidation of rutheno...
1H-NMR spectroscopic studies of anion and solvent effects on mixed-valence iodobiruthenocenium(II, IV) salts
Watanabe, Masanobu,Iwamoto, Toschitake,Sano, Hirotoshi,Motoyama, Izumi
, p. 197 - 202 (1993)
Oxidation of 1,1''-biruthenocene with io...
A New Synthetic Method for the Preparation of Cyclo-olefin Ruthenium Complexes
Pertici, Paolo,Vitulli, Giovanni,Paci, Maurizio,Porri, Lido
, p. 1961 - 1964 (1980)
Hydrated ruthenium trichloride reacts wi...
Microwave-Assisted Synthesis and Transformations of Cationic CpRu(II)(naphthalene) and CpRu(II)(naphthoquinone) Complexes
Bocekova-Gajdo?íkova, Eva,Epik, Bugra,Chou, Jingyu,Akiyama, Katsuhiro,Fukui, Nobuaki,Guénée, Laure,Kündig, E. Peter
, (2019)
Details of the direct synthesis of catio...
Moessbauer Spectroscopic Studies of Tin(IV) Halide Adducts with Ruthenocene and with Ferrocenophanes
Watanabe, Masanobu,Motoyama, Izumi,Sano, Hirotoshi
, p. 2109 - 2114 (1986)
Adducts of tin(IV) halide with ferroceno...
Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride
Rickmeier, Jens,Ritter, Tobias
, p. 14207 - 14211 (2018)
Radiolabeled receptor-binding peptides a...
CYCLOPENTADIENYL-RUTHENIUM AND -OSMIUM COMPLEXES III. CHEMICAL MECHANISM OF DISSOLUTION OF CHLORO(η-CYCLOPENTADIENYL)-BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) IN POLAR SOLVENTS
Wilczewski, Tadeusz
, p. 331 - 340 (1985)
The conversion of CpRuCl(PPh3)2 in boili...
New method for the synthesis of substituted ruthenocenes
Karslyan,Konovalov,Perekalin,Petrovskii,Kudinov
, p. 2032 - 2033 (2008)
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A convenient synthetic route to [CpRu(CH3CN3)]PF6
Trost, Barry M.,Older, Christina M.
, p. 2544 - 2546 (2002)
A convenient synthetic route to [CpRu(CH...
Mixed-Valent Ruthenocene-Vinylruthenium Conjugates: Valence Delocalization Despite Chemically Different Redox Sites
Hassenrück, Christopher,Mang, André,Winter, Rainer F.
, p. 2695 - 2707 (2019)
Ruthenocene-vinylruthenium conjugates Rc...
IMPROVED METHOD FOR SYNTHESIS OF ARENECYCLOPENTADIENYLRUTHENIUM CATIONS
Vol'kenau, N. A.,Bolesova, I. N.,Shul'pina, L. S.,Kitaigorodskii, A. N.,Kravtsov, D. N.
, p. 341 - 348 (1985)
An improved method for the synthesis of ...
A new mechanistic path in the reaction of ruthenium trichloride with silylated cyclopentadienes. Ionic transition metal halides as desilylating agents
Winter,Pirzad,Cao
, p. 1026 - 1027 (1991)
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Organometallic nucleoside analogues: Effect of the metallocene metal atom on cancer cell line toxicity
Ismail, Media K.,Armstrong, Katie A.,Hodder, Samantha L.,Horswell, Sarah L.,Male, Louise,Nguyen, Huy V.,Wilkinson, Edward A.,Hodges, Nikolas J.,Tucker, James H. R.
, p. 1181 - 1190 (2020)
A new chiral organometallic nucleoside a...
CYCLOPENTADIENYL-RUTHENIUM AND -OSMIUM COMPLEXES V. SYNTHESIS, REACTIVITY AND CRYSTAL STRUCTURE DETERMINATION OF CARBONYLCHLORO(η-CYCLOPENTADIENYL)-(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
Wilczewski. Tadeusz,Dauter, Zbigniew
, p. 349 - 356 (1986)
CpRuCl(CO)PPh3 is formed as the result o...
MOLECULAR QUADRUPOLE MOMENTS, MAGNETIC ANISOTROPIES, AND CHARGE DISTRIBUTIONS OF FERROCENE AND RUTHENOCENE.
Ritchie,Cooper,Calvert,Dennis,Phillips,Vrbancich
, p. 5151 - 5219 (1983)
Measurements of the infinite-dilution mo...
Synthesis, Computational Studies, Inelastic Neutron Scattering, Infrared and Raman Spectroscopy of Ruthenocene
Parker, Stewart F.,Butler, Ian R.
, p. 1142 - 1146 (2019)
In this work we report a new and simplif...
NEW HIGH YIELD SYNTHESES OF RUTHENOCENE AND OSMOCENE AND THEIR DECAMETHYL DERIVATIVES. THE CRYSTAL STRUCTURE OF 5-C5Me5)2>
Liles, David C.,Shaver, Alan,Singleton, Eric,Wiege, Manfred B.
, p. C33 - C36 (1985)
Reaction of x> (x > 2; cod = cycloocta-1...
Synthesis, reactivity, and characterization of ruthenocenes bearing pentazincated cyclopentadienyl ligands
Seneviratne, Kapila N.,Winter, Charles H.
, p. 2498 - 2499 (1997)
Treatment of pentakis(chloromercurio)pen...
Octadienediyl Dichlorides of Ruthenium (IV) as Synthetic Reagents in Organoruthenium Chemistry; Isolation of a Protonated 'Open Metallocene' 5-C7H11)2H>
Cox, David N.,Roulet, Raymond
, p. 951 - 953 (1988)
Chloride extraction from 3:ν3-C10H16)Cl2...
Eisen- und Ruthenium-Komplexe mit 1,1-Difluoroethen
Keim, Wilhelm,Fischer, Wolfgang
, p. C20 - C23 (1991)
1,1-Difluorethylene reacts with CpFe(CO)...
Reduction of ruthenium arenecyclopentadienyl complexes reactions induced by electron transfer
Gusev, Oleg V.,Ievlev, Mikhail A.,Peterleitner, Mikhail G.,Peregudova, Svetlana M.,Denisovich, Larisa I.,Petrovskii, Pavel V.,Ustynyuk, Nikolai A.
, p. 57 - 66 (1997)
Ruthenium arenecyclopentadienyl complexe...
REAGENT AND PROCESS FOR THE SITE-SPECIFIC DEOXYFLUORINATION OF PEPTIDES
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Page/Page column 13, (2020/01/31)
The present invention refers to reagents...
1287-13-4 Process route
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0.5[((C5H5)2Ru)2SnCl2](2+)*SnCl5(1-)=(C5H5)2Ru(SnCl4)1.5
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1287-13-4
bis(η5-cyclopentadienyl)ruthenium
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7646-78-8
tin(IV) chloride
| Conditions | Yield |
|---|---|
|
In
acetonitrile;
dissolving Ru-Sn-compound in acetonitrile and standing in air for a fewminutes;;
|
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63767-78-2
ruthenium trichloride
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542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene
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1287-13-4
bis(η5-cyclopentadienyl)ruthenium
| Conditions | Yield |
|---|---|
|
With
zinc;
In
ethanol;
at -60 - 10 ℃;
for 26h;
|
95% |
|
With
zinc;
at 20 ℃;
for 1h;
|
73.5% |
1287-13-4 Upstream products
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63767-78-2
ruthenium trichloride
-
542-92-7
cyclopenta-1,3-diene
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102-54-5
ferrocene
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10049-08-8
ruthenium(III)chloride
1287-13-4 Downstream products
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12093-10-6
ferrocenecarboxaldehyde
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1271-48-3
1,1'-ferrocenyldicarboxaldehyde
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66507-25-3
ruthenocene carboxylaldheyde
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7440-18-8
ruthenium
