Perfect Factory Offer Excellent quality NONAMETHYLTRISILAZANE 1586-73-8 with Safe Shipping
- Molecular Formula: C9H27NSi3
- Molecular Weight: 233.577
- Appearance/Colour: Colorless crystals
- Vapor Pressure: 0.559mmHg at 25°C
- Melting Point: 65-69 °C
- Refractive Index: 1.4550
- Boiling Point: 189.8 °C at 760 mmHg
- PKA: pK1:4.70(+1) (25°C)
- Flash Point: 75.9 °C
- PSA： 3.24000
- Density: 0.801 g/cm3
- LogP: 3.79310
NONAMETHYLTRISILAZANE(Cas 1586-73-8) Usage
InChI:InChI=1/C9H27NSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3
1586-73-8 Relevant articles
[Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction
Araake, Ryoichi,Sakadani, Kazuki,Tada, Mizuki,Sakai, Yoichi,Ohki, Yasuhiro
, p. 5596 - 5606 (2017)
Multiple iron atoms bridged by hydrides ...
Synthesis and Characterization of Bioinspired [Mo2Fe2]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2
Ohki, Yasuhiro,Araki, Yuna,Tada, Mizuki,Sakai, Yoichi
, p. 13240 - 13248 (2017)
The hydride-supported [Mo2Fe2] cluster c...
Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes
Ghana, Priyabrata,Van Krüchten, Franziska D.,Spaniol, Thomas P.,Van Leusen, Jan,K?gerler, Paul,Okuda, Jun
, p. 3231 - 3234 (2019)
By using a triaryl-Tren ligated titanium...
Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes
Eaton, Mary C.,Knight, Brian J.,Catalano, Vincent J.,Murray, Leslie J.
, p. 1519 - 1524 (2020)
We report catalytic silylation of dinitr...
Synthesis of Dinuclear Mo?Fe Hydride Complexes and Catalytic Silylation of N2
Ishihara, Kodai,Araki, Yuna,Tada, Mizuki,Takayama, Tsutomu,Sakai, Yoichi,Sameera,Ohki, Yasuhiro
, p. 9537 - 9546 (2020)
Two transition-metal atoms bridged by hy...
N2 Silylation Catalyzed by a Bis(silylene)-Based [SiCSi] Pincer Hydrido Iron(II) Dinitrogen Complex
Li, Shengyong,Wang, Yajie,Yang, Wenjing,Li, Kai,Sun, Hongjian,Li, Xiaoyan,Fuhr, Olaf,Fenske, Dieter
, p. 757 - 766 (2020)
The bis(silylene)-based SiC(sp3)Si pince...
Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N2 to N(SiMe3)3
Dechert, Sebastian,Demeshko, Serhiy,Gupta, Sandeep K.,Li, Ming,Meyer, Franc
, p. 14480 - 14487 (2021)
Using a pyrazolate-bridged dinucleating ...
N-Substituted hexamethyldisilazanes as new substances for the synthesis of functional films in the system Si-Ge-C-N-H
Sysoev,Nikulina,Kolontaeva,Kosinova,Titov,Rakhlin,Tsyrendorzhieva,Lis,Voronkov
, p. 2501 - 2505 (2011)
N-Organylbis(trimethylsilyl)amines of th...
Synthesis and Reactivity of Iron– and Cobalt–Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation
Imayoshi, Ryuji,Nakajima, Kazunari,Takaya, Jun,Iwasawa, Nobuharu,Nishibayashi, Yoshiaki
, p. 3769 - 3778 (2017)
Iron– and cobalt–dinitrogen complexes be...
New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide and its 4-methoxynaphthalene derivative with hexamethyldisilazane
Kilian, Petr,Marek, Jaromir,Marek, Radek,Tou-In, Jioi,Humpa, Otakar,Novosad, Josef,Woollins, J. Derek
, p. 1175 - 1180 (1998)
Reaction of 2,4-(naphthalene-1,8-diyl)-1...
Dinitrogen Functionalization Affording Chromium Hydrazido Complex
Yin, Jianhao,Li, Jiapeng,Wang, Gao-Xiang,Yin, Zhu-Bao,Zhang, Wen-Xiong,Xi, Zhenfeng
, p. 4241 - 4247 (2019)
A series of trinuclear and dinuclear Cr(...
N2 Reduction into Silylamine at Tridentate Phosphine/Mo Center: Catalysis and Mechanistic Study
Liao, Qian,Saffon-Merceron, Nathalie,Mézailles, Nicolas
, p. 6902 - 6906 (2015)
Transition-metal-catalyzed formation of ...
Fe-Catalyzed Conversion of N2 to N(SiMe3)3 via an Fe-Hydrazido Resting State
Piascik, Adam D.,Li, Ruohao,Wilkinson, Harry J.,Green, Jennifer C.,Ashley, Andrew E.
, p. 10691 - 10694 (2018)
The catalytic conversion of N2 to N(SiMe...
-
Wannagar,Schreiner
, p. 46 (1964)
-
-
Wiberg,Uhlenbrock
, p. 239,242, 246 (1974)
-
Triphos-Fe dinitrogen and dinitrogen-hydride complexes: Relevance to catalytic N2 reduction
Cavaillé, Anthony,Joyeux, Benjamin,Saffon-Merceron, Nathalie,Nebra, Noel,Fustier-Boutignon, Marie,Mézailles, Nicolas
, p. 11953 - 11956 (2018)
The two electron reduction of iron compl...
Cobalt-catalyzed transformation of molecular dinitrogen into silylamine under ambient reaction conditions
Imayoshi, Ryuji,Tanaka, Hiromasa,Matsuo, Yuki,Yuki, Masahiro,Nakajima, Kazunari,Yoshizawa, Kazunari,Nishibayashi, Yoshiaki
, p. 8905 - 8909 (2015)
The first successful example of cobalt-c...
Coupling dinitrogen and hydrocarbons through aryl migration
McWilliams, Sean F.,Broere, Dani?l L. J.,Halliday, Connor J. V.,Bhutto, Samuel M.,Mercado, Brandon Q.,Holland, Patrick L.
, p. 221 - 226 (2020)
The activation of abundant molecules suc...
Catalytic dinitrogen reduction at the molybdenum center promoted by a bulky tetradentate phosphine ligand
Liao, Qian,Saffon-Merceron, Nathalie,Mzailles, Nicolas
, p. 14206 - 14210 (2014)
Stoichiometric reduction of N2 at a Mo c...
Synthesis of a T-Shaped Cobalt(I) Complex and Its Dinitrogen Adduct
Sanz, Corey A.,Stein, Carolin A. M.,Fryzuk, Michael D.
, p. 1465 - 1471 (2020)
The coordination chemistry of the new NN...
An arene-tethered silylene ligand enabling reversible dinitrogen binding to iron and catalytic silylation
Bai, Yunping,Zhang, Jianying,Cui, Chunming
, p. 8124 - 8127 (2018)
An arene-tethered silylene ligand, L (L ...
Latent Nucleophilic Carbenes
Hurieva, Anastasiya,Koidan, Georgyi,Kostyuk, Aleksandr,Kyrylchuk, Andrii A.,Marchenko, Anatoliy,Rozhenko, Alexander B.,Rusanov, Eduard B.,Shvydenko, Kostiantyn
, (2021/12/27)
Using DFT and ab initio calculations, we...
Ketone Enolization with Sodium Hexamethyldisilazide: Solvent- And Substrate-Dependent E- Z Selectivity and Affiliated Mechanisms
Collum, David B.,Woltornist, Ryan A.
, p. 17452 - 17464 (2021/11/04)
Ketone enolization by sodium hexamethyld...
Ammonia Formation Catalyzed by a Dinitrogen-Bridged Dirhenium Complex Bearing PNP-Pincer Ligands under Mild Reaction Conditions**
Egi, Akihito,Kuriyama, Shogo,Meng, Fanqiang,Nishibayashi, Yoshiaki,Tanaka, Hiromasa,Yoshizawa, Kazunari
supporting information, p. 13906 - 13912 (2021/05/13)
A series of rhenium complexes bearing a ...
1586-73-8 Process route
-
-
79345-35-0
Lithium-tris(trimethylsilyl)tetrazenid
-
-
1586-73-8
tris(trimethylsilyl)amine
-
-
4648-54-8
trimethylsilylazide
-
![N-lithio-N,N',N'-[tris(trimethylsilyl)]hydrazide](/upload/2026/5/ad72c7673f2d473cb47fa9f7633299f1_787e52ad-1ee4-4109-97a5-5aee9325c137.png)
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22846-03-3
N-lithio-N,N',N'-[tris(trimethylsilyl)]hydrazide
-
-
4039-32-1
lithium hexamethyldisilazane
| Conditions | Yield |
|---|---|
|
In
benzene;
at 25 ℃;
for 6h;
|
1.5 mmol
0.2 mmol 0.3 mmol 0.3 mmol |
-
-
N,N,N′,1,1,1-hexamethylsilanecarboximidamide
-
-
2083-91-2
N,N-Dimethyltrimethylsilylamine
-
-
1586-73-8
tris(trimethylsilyl)amine
-
-
1609-01-4
N1 ,N1 ,N2 -Trimethylformamidine
-
-
C14 H38 N2 Si3
| Conditions | Yield |
|---|---|
|
With
dimethyl amine;
In
diethyl ether;
at 0 - 30 ℃;
under 1 - 10 Torr;
|
6 g
2.8 g |
1586-73-8 Upstream products
-
75-77-4
chloro-trimethyl-silane
-
4039-32-1
lithium hexamethyldisilazane
-
1000-70-0
bis(trimethylsilyl)carbodi-imide
-
109-99-9
tetrahydrofuran
1586-73-8 Downstream products
-
41309-92-6
N-(Difluorphosphoryl)bis(trimethyl)silylamin
-
120263-52-7
N'-tosyl-N-(trimethylsilyl)sulfur diimide
-
503027-47-2
N,N'-bis(trimethylsilyl)sulfurdiimide
-
17599-59-6
diphenylmethyleneaminotrimethylsilane
